History of mineral processing in South Australia - Ammonia leaching of oxide copper ores by Samin Limited at Burra, SA.
Created: 29 Oct 2024 Revised: 07 Dec 2024

When Samin Ltd decided in 1969 to re-open the Burra mine for open pit extraction and onsite processing of the substantial remnant orebody of oxidised copper minerals, it was initially envisaged that the copper recovery method would involve an acid...

When Samin Ltd decided in 1969 to re-open the Burra mine for open pit extraction and onsite processing of the substantial remnant orebody of oxidised copper minerals, it was initially envisaged that the copper recovery method would involve an acid leach and cementation process, with the sale of the product copper cement to a smelter. This route was soon rejected due to the presence of a high proportion of acid-consuming host rocks. The Australian Mineral Development Laboratories (AMDEL) were commissioned to develop a treatment route, under the guidance of their Director, Mr N. Draper. Mr Draper joined Samin in 1970 as Chief Metallurgist and Director, and following the takeover became Chief Metallurgist and Associate Director of Poseidon. The options of acid leaching and flotation of the ore were soon rejected due to high acid requirements and low copper recoveries, respectively. The ammonia leaching route was selected for development and the process that subsequently evolved (Stage 1) was developed from reports on the Kennecott Copper Corporation's operation at Kennecott in Alaska in the early 1900s, and on the Nicaro nickel operation in Cuba. The Stage 1 process operated from early 1971 to October 1973, when it was shut down for the commissioning of the whole-of-ore treatment process (Stage 2). The author saw the last 3 months of the Stage 1 operation, and his description is based on observations made at the time, on verbal discussions with the initial operating crew, and on reports of the operations. The plant was constructed and commissioned under the guidance of the Manager of Operations, Mr H.J. Rich, and the Maintenance Engineer Mr N. van Buuren. In essence, the Stage 1 operation developed and designed by AMDEL was a direct ammoniacal percolation vat leach process of a deslimed crushed ore, developed from operational reports for the Kennecott operation in Alaska. The Stage 1 plant flow sheet is shown in the Appendix. The technology was developmental, with no similar process in operation in the world, and understandably numerous problems were encountered. This report discusses and describes the operation and the problems encountered, along with variations from the original design. The Burra ore minerals were principally malachite (CuCO3. Cu(OH)2), azurite (2CuCO3.Cu(OH)2), and chrysocolla (CuSiO3.2H2O), with a cuprite (Cu2O) proportion increasing at depth. Laboratory leaching tests defined that these minerals, excepting chrysocolla, were highly soluble in ammoniacal liquors. Chrysocolla was insoluble along with all the remaining gangue materials. It was therefore essential that Stage 1 ore mining avoided the high chrysocolla areas in the mine. Alternative processes were being investigated at the time for the future treatment of chrysocolla and of fine ores trapped in montmorrillonite clay-hosted gangue, as it was realised that the presence of clay would inhibit solid/liquid separation of leached slurries. Laboratory and pilot plant research into a process to treat the whole of the run-of-mine ore continued for two years in parallel with the Stage 1 operation. The flotation option was revisited, along with reduction roasting of the ore. Encouraging reduction roasting results had been show in laboratory tests, which were confirmed with pilot testwork in Europe and America at the engineering company laboratories of Lurgi and Envirotech, respectively. Natural gas would be available in the area at the time of a roaster installation, and there was great interest in the cleaner fuel. Again, the technology was ultimately successfully developed without reference to any similar operation in the world (except perhaps the Nicaro ammonia leaching nickel plant in Cuba, access to which was not available at the time). This report particularly discusses and describes the Burra Stage 2 operation and the numerous problems encountered. Stage 2 commenced its commissioning phase in October, 1973, after a 14 day plant closure to cut-in new equipment above that used in Stage 1. The commissioning phase extended for almost 3 years before achieving economic viability. Stage 2 ore roasting ceased due to exhaustion of ore reserves on February 25, 1983. A 1976 flowsheet and equipment description is also presented in the Appendix.

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About this record

Record No mesac19414
Topic Geoscientific Information
Type of Resource Document
Category Type
Document Type Departmental Publication - Other
Contributor
Sponsor
Tenement
Tenement Holder
Operator
Geological Province Adelaide Geosyncline
Mine Name Burra mine;Morphetts shaft;Graves shaft;Bon Accord mine
Stratigraphy
Commodity copper
Notes
Notes: The importance of the Burra Burra mine to the development of South Australia has been well documented by others, in particular a noted historian, Ian Auhl.  This major high grade oxide copper resource was mined during the period 1845 to...

Notes: The importance of the Burra Burra mine to the development of South Australia has been well documented by others, in particular a noted historian, Ian Auhl. This major high grade oxide copper resource was mined during the period 1845 to 1877 and the mine was commonly referred to as the Monster Mine. During this period, 234,648 tonnes of ore was mined at a grade of 22% copper. The mine remained closed (apart from two minor unsuccessful attempts at revival at the turn of the century and in the 1920s) until Samin Ltd was formed in 1969. At this time the opportunity presented itself when Broken Hill South Ltd relinquished the leases they held over the mine, whereupon their then Chief Geologist Mr B.R. Lewis resigned: he acquired the Burra leases and formed Samin Ltd with Mr E.O. Myers and Mr A.O. Thomas. Poseidon Ltd acquired 100% ownership of Samin soon after its formation, and Messrs Lewis and Myers became joint Managing Directors and Mr Thomas the Company Secretary of Poseidon Ltd. A unique chemical business was developed by Samin during its Burra project Stages 1 & 2 operating periods detailed in this historical presentation, and at the end of the mineable ore resource many opportunities were explored to maintain an ongoing business. Local copper scrap and cement production were the initial materials used, and these were expanded to treat a range of raw materials. Cupric oxide is still being produced at the plant in Burra today. Geographic Locality: Burra;Burra North;Kingston Fault Doc No: Env 09859

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Language English
Metadata Standard ISO 19115-3

Citations

Use constraints License
License Creative Commons Attribution 4.0
Persistent identifier https://pid.sarig.sa.gov.au/document/mesac19414
Citation Armstrong, G.J. History of mineral processing in South Australia - Ammonia leaching of oxide copper ores by Samin Limited at Burra, SA. Departmental Publication - Other
https://pid.sarig.sa.gov.au/document/mesac19414

Technical information

Status
Maintenance and Update Frequency
Geographic Reference GDA2020 (EPSG:7844)
Geo bounding box {"type":"Polygon","coordinates":[[[138.5,-34],[139,-34],[139,-33.5],[138.5,-33.5],[138.5,-34]]]}
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